SELECT 
  lang.name, 
  IF(
    cscart_ult_language_values.value IS NULL, 
    lang.value, cscart_ult_language_values.value
  ) as value 
FROM 
  cscart_language_values lang 
  LEFT JOIN cscart_ult_language_values ON cscart_ult_language_values.name = lang.name 
  AND company_id = 1 
  AND cscart_ult_language_values.lang_code = lang.lang_code 
WHERE 
  lang.lang_code = 'en' 
  AND lang.name IN (
    'stay_connected', 'exclusive_promotions', 
    'exclusive_promotions_content', 
    'subscribe', 'stay_connected', 'exclusive_promotions', 
    'exclusive_promotions_content', 
    'subscribe'
  )

Query time 0.00076

JSON explain

{
  "query_block": {
    "select_id": 1,
    "table": {
      "table_name": "cscart_ult_language_values",
      "access_type": "system",
      "possible_keys": ["PRIMARY"],
      "rows": 0,
      "filtered": 0,
      "const_row_not_found": true
    },
    "table": {
      "table_name": "lang",
      "access_type": "range",
      "possible_keys": ["PRIMARY"],
      "key": "PRIMARY",
      "key_length": "392",
      "used_key_parts": ["lang_code", "name"],
      "rows": 4,
      "filtered": 100,
      "index_condition": "lang.lang_code = 'en' and lang.`name` in ('stay_connected','exclusive_promotions','exclusive_promotions_content','subscribe','stay_connected','exclusive_promotions','exclusive_promotions_content','subscribe')"
    }
  }
}